Ethyl‐β‐chlorovinyl ether
- 1 January 1951
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 70 (4) , 289-296
- https://doi.org/10.1002/recl.19510700403
Abstract
The preparation of ethyl‐β‐chlorovinyl ether from the readily available dichloroacetal is reported. Careful fractionation of the product yields the pure cis‐ and trans‐isomers of which only the cis‐isomer gives a high yield (76%) of ethoxy‐acetylene on heating with potassium hydroxide.The corresponding ethyl‐β‐bromovinyl ether has likewise been separated into cis‐ and trans‐isomers.Keywords
This publication has 2 references indexed in Scilit:
- Acetylenic Ethers. II. Ethoxy- and Butoxy-acetyleneJournal of the American Chemical Society, 1942
- The Kinetics of the Thermal Isomerization of trans-DichloroethyleneJournal of the American Chemical Society, 1940