The Effects of Interactions in Real Polymer Chains
- 1 February 1953
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (2) , 205-208
- https://doi.org/10.1063/1.1698857
Abstract
The effect of interactions between the segments of a polymer chain on the size of the molecule has been calculated. Two approaches have been used. The first is a direct probability calculation using an exponential interaction energy between segments. The second follows the original approach of Flory but solves the problem to a different approximation. Both methods lead to essential agreement with Flory's result for small and moderate interactions. A probable reason for the spurious results found by others is proposed.Keywords
This publication has 6 references indexed in Scilit:
- Sedimentation Behavior of Flexible Chain Molecules: PolyisobutyleneThe Journal of Chemical Physics, 1952
- The Excluded Volume of Polymer ChainsThe Journal of Chemical Physics, 1952
- Viscosity of dilute and moderately concentrated polymer solutionsJournal of Research of the National Bureau of Standards, 1951
- Treatment of Intrinsic ViscositiesJournal of the American Chemical Society, 1951
- The Configuration of Real Polymer ChainsThe Journal of Chemical Physics, 1949
- Stochastic Problems in Physics and AstronomyReviews of Modern Physics, 1943