An extended X-ray absorption fine structure study of penta-amminecopper(II) bis(tetrafluoroborate): evidence for five equal bond lengths
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 4,p. 645-648
- https://doi.org/10.1039/dt9830000645
Abstract
The extended X-ray absorption fine structure spectra of powered [Cu(NH3)5][BF4]2 have been measured at room temperature and at 77 K using synchrotron radiation. Standard Fourier-transform and least-squares fitting methods {utilising [Cu(en)2][BF4]2(en = ethylenediamine) as a model complex for extracting amplitude and phase parameters for Cu–N bonds} demonstrate that in each case only a single shell is present about the metal ion, i.e. all five Cu–N bonds are of equal length.Keywords
This publication has 0 references indexed in Scilit: