Reaction of triplet aryl nitrenes and azides with molecular oxygen
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 964-966
- https://doi.org/10.1039/c39720000964
Abstract
Photolysis of aryl azides in the presence of oxygen gives nitro-compounds via a triplet nitrene and, in the case of para-substituted azides, also the azoxy-compound, probably via the nitroso-compound from the reaction of excited azide with oxygen, while triethyl phosphite deoxygenation of nitrosobenzene under oxygen also gave some nitrobenzene.Keywords
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