Asymmetric induction in the rearrangement of monocyclic endoperoxides into γ-hydroxy-αβ-unsaturated aldehydes
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1062-1063
- https://doi.org/10.1039/c39800001062
Abstract
The endoperoxide obtained by addition of singlet oxygen to 2,3-bis(methylene)-7-oxanorbornane is isomerised to the chiral γ-hydroxy-αβ-unsaturated aldehyde by catalytic amounts of various natural bases with an enantiomeric excess ranging up to 46%.Keywords
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