Correlation of specific migration(Cf)of plastics additives with their initial concentration in the polymer(Cp)

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Abstract
The first list of plastics additives which may be assigned restrictions in a future amendment to Directive 90/128/ EEC is likely to contain over 200 substances. If food consumption factors are taken into account many compounds on this list could have restrictions removed but there would, without doubt, still be many additives with restrictions. Extensive migration testing of food contact plastics containing restricted additives to ensure compliance would be required. These limits would be difficult to enforce, add significant cost burdens on the packaging industry and, for these reasons, may not provide improved consumer safeguards. An alternative means of control has been proposed based upon polymer composition. However, in order to support such a scheme a reliable correlation between migration of additives to their composition in the polymer must be demonstrated. There has been strong interest in establishing this relationship and a feasibility project to investigate the specific migration of four commonly used additives has been successfully completed. The study was initially funded for 1 year, by the Ministry of Agriculture, Fisheries and Food (MAFF) and industry. Analytical methods to determine the additives in food simulants have been developed and linear correlations have been demonstrated between the concentration of all four additives and their specific migration levels for each polymer studied. Experimental migration data have been compared with those generated by mathematical models.

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