Vacuum ultraviolet absorption spectra of solid OCS at 53 K
- 15 December 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 63 (12) , 5126-5130
- https://doi.org/10.1063/1.431320
Abstract
Photoabsorption spectra of thin films of solid OCS were obtained in the 110–300 nm wavelength region. The absorption intensities and excitation energies of the 1Δ←1Σ+ and 1Π←1Σ+ transitions were changed in the solid, and higher energy Rydberg absorption was reduced and diffuse. Three absorption continua not normally observed in the gas phase were found at 4.3, 4.7, and 6.9 eV and assigned to the 3Σ+←1Σ+, 1Δ←1Σ+, and 3Π←1Σ transitions, respectively.Keywords
This publication has 14 references indexed in Scilit:
- Vacuum ultraviolet absorption spectra of solid N2O and CO2 at 53 KThe Journal of Chemical Physics, 1975
- Photoabsorption of solid carbon dioxide from 7 to 12 eVThe Journal of Chemical Physics, 1974
- Extravalence molecular excitations in inert matricesThe Journal of Chemical Physics, 1973
- Inference of “forbidden character” in the 2000 Å transitions of the N2O and OCS moleculesJournal of Molecular Spectroscopy, 1972
- Vacuum ultraviolet spectroscopy of deep lying impurity states in solid CF4Chemical Physics Letters, 1972
- Ultraviolet Absorption Spectrum of Carbonyl SulfideThe Journal of Chemical Physics, 1970
- Electronic transitions of CS2 and OCS trapped in solid matrices and Rydberg series in dense mediaChemical Physics Letters, 1969
- The Reactions of Sulfur Atoms. VII. The Ultraviolet Spectrum, the Photolysis, and the Mercury Sensitization of Carbonyl SulfideJournal of the American Chemical Society, 1966
- Schumann—Runge Bands of O2 in Solid Phases: Spectroscopic Measurement of Intermolecular PotentialsThe Journal of Chemical Physics, 1965
- Higher Ionization Potentials of Linear Triatomic Molecules. II. CS2, COS, and N2OThe Journal of Chemical Physics, 1960