Origin of the electron spin resonance signal in diamagnetic phthalocyanins
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 23,p. 2360-2364
- https://doi.org/10.1039/dt9770002360
Abstract
Detailed analysis of the e.s.r. signal observed in some diamagnetic phthalocyanins and metal-free tetraphenylporphyrin suggests that the cause is various charge-transfer interactions between phthalocyanin or porphyrin cations and dioxygen anions stabilised by the surface of the diamagnetic host.Keywords
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