Low-temperature oxygenation of methane into formic acid with molecular oxygen in the presence of hydrogen catalysed by Pd0.08Cs2.5H1.34PVMo11O4 0

1 January 1997

journal article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 14,p. 1295-1296
https://doi.org/10.1039/a702514i

Abstract

The title reaction is catalysed by Pd0.08Cs2.5H1.34PVMo11O4 0 at temperatures as low as 423–593 K, and the catalytic rate, which reached a maximum at 573 K, is 1.2 × 10-4 mol h-1 g-1, ca. 3 × 102 times higher than FePO4, the most active catalyst previously reported.

Keywords

METHANE

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