ON THE SPIN–ORBIT INTERACTION IN DIATOMIC MOLECULES. I

1 March 1958

journal article
Published by Canadian Science Publishing in Canadian Journal of Physics

Vol. 36 (3) , 309-328
https://doi.org/10.1139/p58-034

Abstract

The purpose of the present paper is to give further details of an investigation of the spin–orbit interaction in diatomic molecules. The first part of the paper deals with perturbations between states of odd multiplicity in a two-electron system. With the aid of the matrix elements which have been obtained, a comparison of the perturbations in the various components of a given state and in some cases a comparison of perturbations in two different states is possible. Also for certain cases it has been possible to establish relationships between the matrix elements which give the magnitude of the perturbations and experimentally measurable molecular constants of the perturbed states.

Keywords

This publication has 2 references indexed in Scilit:

The Near Ultra-Violet Band-System (D-X) of Silicon Monosulphide
Proceedings of the Physical Society. Section A, 1952
On $Λ$ -Type Doubling in ${}^{3}Π$ States of Diatomic Molecules Intermediate Between Hund's Cases $a$ and $b$
Physical Review B, 1936