The formation of a nitrogen to carbon bond in a reaction of a dinitrogen complex
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 444-445
- https://doi.org/10.1039/c39720000444
Abstract
Organic acid chlorides, RCOCl, react with trans-[W(N2)2(dpe)2](dpe = Ph2PCH2CH2PPh2) to produce complexes [(dpe)2Cl2W(N2HCOR)] from which HCl can be removed to form chelated aroyl- and acyl-azo-N,O-complexes, [(dpe)2ClW(–N = N–COR)].Keywords
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