Intramolecular Magnetic Interaction of Transition Metal ions in Complexes Containing Pyrimidine or Pyrazine as a Bridging Ligand
- 1 September 1993
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals
- Vol. 233 (1) , 345-350
- https://doi.org/10.1080/10587259308054976
Abstract
The magnetic interactions between transition metal ions bridged with 4,6-pyrimidinedicarboxylate, 4,6-dipyridylpyrimidine, 23-pyrazine-dicarboxylate, or 2,3-dipyridylpyrazine were studied. Several dinuclear complexes containing Cu2+, Ni2+, Co2+, or Mn2+ were synthesized and characterized. They were antiferromagnetically coupled in all cases.Keywords
This publication has 6 references indexed in Scilit:
- Bis[3-tert-butyl-5-(N-oxy-tert-butylamino)phenyl] nitroxide in a quartet ground state: a prototype for persistent high-spin poly[(oxyimino)-1,3-phenylenes]Journal of the American Chemical Society, 1991
- Control of the intramolecular magnetic interaction by the spin polarization of dπ-electrons: ferromagnetic interaction between iron centres through an organic bridging ligandJournal of the Chemical Society, Chemical Communications, 1991
- Magnetic properties and crystal structure of (2,3-pyrazinedicarboxylato)copper(II) hydrochloride: a pyrazine bridged ferromagnetic linear chainInorganic Chemistry, 1982
- PMR and ESR of copper(II) complexes incorporating pyrazine analogs as bridging ligandsInorganica Chimica Acta, 1979
- The preparation and properties of certain pyridylpyrimidines and bidiazines as potential chelating agents for iron(II)The Journal of Organic Chemistry, 1967
- 109. Pyrimidines. Part X. Pyrimidine, 4 : 6-dimethylpyrimidine, and their 1-oxidesJournal of the Chemical Society, 1959