Very high diastereofacial selectivity in the nucleophilic epoxidation of N-(p-tolylsulphonyl)vinylsulphoximines
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 1,p. 200-202
- https://doi.org/10.1039/p19900000200
Abstract
Nucleophilic epoxidation of N-(p-tolylsulphonyl)vinylsulphoximines (6) using lithium t-butyl hydroperoxide proceeds with very high diastereofacial selectivity, the sense of which was established by a single crystal X-ray structure determination, to give N-(p-tolylsulphonyl)phenylsulphoximino-oxiranes (5) in good yield.Keywords
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