Electrostatic vs. orbital effects as stereoinductive factors in nucleophilic additions to the endo-substituted norbornan-7-one ring system
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 12,p. 2189-2190
- https://doi.org/10.1039/p29950002189
Abstract
Polar-field susceptibility parameters as well as a 13C NMR probe based on the transmission of polar substituent effects in endo-norbornan-7-ones points to the involvement of electrostatic effects in determining π-face selectivities during nucleophilic additions to this ring system.Keywords
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