The Design, Synthesis and Characterization of the Molecular Components of Organic Conductors
- 1 May 1982
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals
- Vol. 86 (1) , 1-26
- https://doi.org/10.1080/00268948208073664
Abstract
Following an examination of the design constraints for the formulation of good organic conductors and a brief review of the synthesis of heterocyclic selenium π-donors such as TMTSF and the zero pressure organic superconductor (TMTSF)2ClO4, the preparation and characterization of five new π-donors is outlined. These new π-donors are dithiophenotetrathiafulvalene, (DTTTF), dithiophenotetraselenafulvalene (DTTSF), dibenzotetraselenafulvalene (DBTSF), dibenzotetratellurafulvalene (DBTTeF), and benzotrisselenophene (BTS).This publication has 55 references indexed in Scilit:
- A reversible field induced phase transition in semiconducting films of silver and copper TNAP radical-ion saltsJournal of the American Chemical Society, 1980
- Diamagnetic AC susceptibility in the quasi-one dimensional organic conductor : (TMTSF)2PF6Journal de Physique Lettres, 1980
- Exocyclic benzenes. Synthesis and properties of benzo[1,2-c:3,4-c':5,6-c'']trithiophene, a tristhiahexaradialeneJournal of the American Chemical Society, 1978
- Organic alloys: synthesis and properties of solid solutions of tetraselenafulvalene-tetracyano-p-quinodimethane (TSeF-TCNQ) and tetrathiafulvalene-tetracyano-p-quinodimethane (TTF-TCNQ)Journal of the American Chemical Society, 1977
- Electrical conductivity of tetrathiafulvalenium-tetracyanoquinodimethanide (TTF-TCNQ)Physical Review B, 1976
- Synthesis of .DELTA.2,2'-bis(1,3-benzodithiolidene) derivatives and complex salts therefrom with 7,7,8,8-tetracyanoquinodimethaneThe Journal of Organic Chemistry, 1976
- X-Ray crystal structure of the organic conductor from 2,2′-bi-(2,4-diselenabicyclo[3.3.0]octylidene) and 7,7,8,8-tetracyano-p-quinodimethane (HMTSF–TCNQ)Journal of the Chemical Society, Chemical Communications, 1976
- Photoelectron and electronic absorption spectra of tetrathiafulvalene and related compoundsBerichte der Bunsengesellschaft für physikalische Chemie, 1975
- Synthesis of the organic conductor tetramethyltetraselenofulvalenium 7,7,8,8-tetracyano-p-quinodimethanide (TMTSF–TCNQ)[4,4′,5,5′-tetramethyl-Δ2,2′-bis-1,3-diselenolium 3,6-bis-(dicyanomethylene)cyclohexadienide]Journal of the Chemical Society, Chemical Communications, 1974
- Electron transfer in a new highly conducting donor-acceptor complexJournal of the American Chemical Society, 1973