Temperature Dependence of the Kinetics of Elementary Combustion Reactions of Refractory Species
- 1 November 1986
- journal article
- research article
- Published by Taylor & Francis in Combustion Science and Technology
- Vol. 50 (1) , 151-162
- https://doi.org/10.1080/00102208608923930
Abstract
The dependence of the rate coefficients of gas—phase oxidation reactions of monatomic and diatomic refractory species on temperature is discussed. Examples given pertain primarily to Al and B species reactions in the 300–1900 K range. These reactions show a wide variety of ln k(T) vs. T—1 behavior patterns. It is shown that, because of this variety, it is not yet possible to make reliable predictions regarding reactions for which no experimental data on temperature dependence are available. However, some guidance is given toward making preliminary estimates. Quantitative kinetic data on the reactions are given and the importance of their thermochemistry is discussed. The experimental method (HTFFR) used to obtain these data is briefly reviewed.Keywords
This publication has 30 references indexed in Scilit:
- Temperature dependence of the absolute third-order rate constant for the reaction between Na + O2+ N2over the range 571–1016 K studied by time-resolved atomic resonance absorption spectroscopyJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1985
- A direct kinetic study of the reaction K + OH + He → KOH + He by time-resolved molecular resonance-fluorescence spectroscopy, OH(A2∑+–X2Π), coupled with steady atomic fluorescence spectroscopy, K(52PJ–42S1/2)Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1984
- Matrix reactions of molecular oxygen and ozone with aluminum atomsThe Journal of Physical Chemistry, 1983
- Possible role for metals in stratospheric chlorine chemistryNature, 1981
- Chemistry of meteor metals in the stratosphereGeophysical Research Letters, 1979
- Non-Arrhenius behavior in bimolecular reactions of the hydroxyl radicalThe Journal of Physical Chemistry, 1979
- Gas phase chemical kinetics of sodium in the upper atmosphereNature, 1976
- Af terburning Predictions for Metal-Modified Propellant Motor ExhaustsAIAA Journal, 1976
- The Chemistry of Metallic Elements in the Ionosphere and MesosphereChemical Reviews, 1973
- The kinetics of combustion of gaseous sulphur compoundsCombustion and Flame, 1972