The stability of the phase III structure in solid CH4–CD4 mixtures
- 1 April 1982
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 76 (7) , 3843-3844
- https://doi.org/10.1063/1.443434
Abstract
These phase diagrams of solid CH4–CD4 mixtures has been explored at low CD4 concentrations (below 30% CD4). The phase III structrue of solid methane is found to be metastable below a CD4 concentration of about 15 mol %.Keywords
This publication has 10 references indexed in Scilit:
- Tunneling states in phase III of solid partially deuterated methanes. Determination by inelastic neutron scattering and correlation with thermodynamic dataThe Journal of Chemical Physics, 1981
- An X-ray powder diffraction study of crystalline α-methane-d4Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1980
- Tunnel splittings in solid CD4 estimated from heat capacity dataThe Journal of Chemical Physics, 1980
- Rotational tunneling in methane (CD4): Isotope effectThe Journal of Chemical Physics, 1980
- Theory of phase transitions in solid methanes. XII. Orientational order of molecules in phase IIIThe Journal of Chemical Physics, 1979
- Tunneling states and nuclear spin conversion in solid CH3DThe Journal of Chemical Physics, 1978
- Neutron scattering and proton spin conversion in solid CH4Canadian Journal of Physics, 1977
- Theory of phase transitions in solid methanes. X. Centering around Phase II in solid CH4The Journal of Chemical Physics, 1977
- Structure and Phase Transitions of Solid Heavy Methane (CD4)The Journal of Chemical Physics, 1972
- Theory of Phase Transitions in Solid Methanes. IVProgress of Theoretical Physics, 1969