Role of angular momentum in unimolecular kinetics: Kinetic energy release in fragmentation of C4H6+
- 1 June 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (11) , 5100-5104
- https://doi.org/10.1063/1.433766
Abstract
The kinetic energy release distributions in the fragmentation C4H6+→C3H3++CH3 at selected energies are reported and are compared with the analogous distributions from ’’metastable’’ C4H6+ and from C2H2++C2H4 collision complexes. The data seem to reflect the role of angular momentum in the collision experiments, as predicted by the Langevin model of the quasiequilibrium theory.Keywords
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