Palladium-Catalyzed Cross Coupling of 7-Iodo-2’-deoxytubercidin with Terminal Alkynes
- 1 June 1996
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1996 (06) , 726-730
- https://doi.org/10.1055/s-1996-4282
Abstract
The 7-alkynyl-2’-deoxytubercidins (7-deaza-2’-deoxyadenosines) 7-17 have been prepared by the Pd(0)/Cu(I)-catalyzed cross coupling of 7-iodo-2’-deoxytubercidin (2d) with terminal alkynes. The coupling products include 17α-ethynyltestosterone and 17α-ethynylestradiol derivatives (16, 17).Keywords
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