Microwave Spectrum, Barrier to Internal Rotation, and Dipole Moment of Cis-Crotononitrile
- 15 May 1963
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 38 (10) , 2548-2552
- https://doi.org/10.1063/1.1733539
Abstract
The microwave spectrum of cis‐CH3CH=CHCN has been measured and assigned in the region 8–34 kMc/sec. The transitions were split by tunneling of the methyl group through the potential barrier to internal rotation. From these separations the barrier was determined as 1400 cal/mole. The total dipole moment is 4.08 D.Keywords
This publication has 9 references indexed in Scilit:
- Microwave Spectrum and Barrier to Internal Rotation of cis-1-FluoropropyleneThe Journal of Chemical Physics, 1962
- Molecular Structure of PropyleneThe Journal of Chemical Physics, 1961
- Microwave Spectrum of trans-CrotononitrileThe Journal of Chemical Physics, 1960
- Calculation of Energy Levels for Internal Torsion and Over-All Rotation. IIIThe Journal of Chemical Physics, 1959
- Microwave Spectrum, Molecular Structure of Vinyl Cyanide and a Summary of CC, CH Bond Lengths in Simple MoleculesThe Journal of Chemical Physics, 1959
- Microwave spectrum, dipole moment, and internal barrier of 2-fluoropropeneJournal of Molecular Spectroscopy, 1959
- Note on the Determination of Molecular Structure from Spectroscopic DataThe Journal of Chemical Physics, 1958
- Microwave Spectrum and Barrier to Internal Rotation for Trans-Fluoro-PropyleneThe Journal of Chemical Physics, 1957
- Microwave Spectra of Molecules Exhibiting Internal Rotation. I. PropyleneThe Journal of Chemical Physics, 1957