The Stereochemistry of Organometallic Compounds. XLII. The Preparation of [2,1-b]Quinazolines Involving Rhodium-Catalysed Hydroformylation of 2-Amino-N-Alkenylbenzylamines
- 1 January 1995
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 48 (12)
- https://doi.org/10.1071/ch9952023
Abstract
Rhodium-catalysed reactions of 2-amino-N-alkenylbenzylamines with H2/CO give hexahydro-pyrrolo- and hexahydropyrido -[2,1-b] quinazolines. Reactions of N-allyl derivatives give a single regioisomer, and reactions of but-3-enyl analogues give mixtures of pyrrolo and pyrido derivatives. Some reactions give significant amounts (10-30%) of tetrahydro derivatives. The origin of these compounds remains unclear.Keywords
This publication has 0 references indexed in Scilit: