Synthesis and Photochemical Properties of Covalently-Linked Dimers of Ruthenium(II) Tris (Bipyridine) Complex: Comparison with Ru(II)(bpy)2(Poly-4-Methyl-4′-Vinylbipyridine)
- 1 January 1988
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 25 (10-11) , 1263-1274
- https://doi.org/10.1080/00222338808053420
Abstract
Covalently linked dimers of Ru(bpy)3 2+ (3 and 4) connected by two or three carbon atoms were synthesized as models for Ru(bpy)3 2+-containing vinyl polymer (1). The luminescence properties of 3 and 4 were compared with those of its component monomer, 4,4′-dimethyl-2,2′-bipyridine-bis(2,2′-bipyridine)ruthenium(II) complex (2). In excited 3 and 4, intramolecular interaction leading to enhanced quenching was not observed. Electron-transfer quenching of the excited dimer with methylviologen (MV2+) and the zwitterionic viologen, 1,1′-bis(3-sulfopropyl)4,4′-bipyridinium (SPV), was studied and compared with that of 1 and 2. The low quenching efficiency in 1, 3, and 4 systems can be ascribed to the steric hindrance of unexcited ruthenium complex. Energy migration between ruthenium complexes in the excited 1, 3, and 4 can be ruled out from the kinetic evidence.Keywords
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