Stereoselectivity in the synthesis of 2,5-disubstituted pyrrolidines
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 243-244
- https://doi.org/10.1039/c39870000243
Abstract
Under homogeneous conditions, the silver(I)-catalysed cyclisation of the allenic amine derivatices (3a–c), thogh not (3d), is stereoselective giving cis-2,5-disubstituted pyrrolidines in high yield; cyclisation on (3a), using a heterogeneous silver(I)-catalyst, is nonstereoselective.Keywords
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