Designed Coupling of C1 Ligands: Organometallic Model Reactions
- 1 September 1991
- journal article
- highlight
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 30 (9) , 1119
- https://doi.org/10.1002/anie.199111191
Abstract
With the planned synthesis of thermally stable, mononuclear bis(carbyne) complexes and the subsequent CC coupling of the two carbyne ligands to give an alkyne, F. Filippou et al. have been able to fully confirm the mechanism of C1 + C1‐coupling reactions using tungsten complexes. This mechanism could also play a role in the CC‐coupling reactions of carbonyl‐with carbonyl‐ and of carbonyl‐with isocyanide‐ligands to give the corresponding alkyne ligands (see also Communication on p. 1167ff.).Keywords
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