Fast atom bombardment, frit fast atom bombardment and electrospray ionization mass spectrometric study of organic salts C2+ 2X−: Matrix and anion effects
- 1 July 1995
- journal article
- Published by Wiley in Journal of Mass Spectrometry
- Vol. 30 (7) , 985-992
- https://doi.org/10.1002/jms.1190300708
Abstract
The fast atom bombardment (FAB), frit‐FAB and electrospray ionization mass spectra of bis‐ammonium salts, C2+ 2X−, were compared. The most informative spectra were the FAB mass spectra with m‐nitrobenzyl alcohol as matrix and the Frit‐FAB mass spectra. The nucleophilic character of the iodine anion was established.Keywords
This publication has 23 references indexed in Scilit:
- Spectres de Masse FAB en Mode Positif de Cations Hétérocycliques Doublement Charges Apparentes au Dibenzo[a,e]CyclooctaneBulletin des Sociétés Chimiques Belges, 1991
- Secondary ion mass spectrometry of dispirotripiperazinium compoundsJournal of Mass Spectrometry, 1990
- Mass spectrometry of labile onium ions and carbocation salts. Study by desorption‐ionization mass spectrometry: Fast atom bombardment, field desorption and 252Cf plasma desorption time‐of‐flight mass spectrometryJournal of Mass Spectrometry, 1988
- Fast atom bombardment mass spectrometry: a useful technique for structural characterization of pyrylium, thiopyrylium, and pyridinium cationsJournal of the Chemical Society, Perkin Transactions 2, 1987
- Thermospray mass spectrometry of diazonium and di-, tri- and tetra-quaternary onium saltsJournal of Mass Spectrometry, 1985
- Fast atom bombardment and laser desorption mass spectrometry for determination of alkyltriphenylphosphonium saltsAnalytical Chemistry, 1985
- Doubly-charged ions in desorption mass spectrometryAnalytical Chemistry, 1983
- Fragment ion formation of quaternary ammonium salts under fast atom bombardment and field desorption collisionally activated dissociation conditionsJournal of Mass Spectrometry, 1983
- Fast atom bombardment mass spectrometry of saltsJournal of Mass Spectrometry, 1983
- Secondary ion mass spectra of diquaternary ammonium saltsAnalytical Chemistry, 1980