Abstract
An isospin analysis of Bππ decays yields sin2α, where αarg[VtdVtb*/(VudVub*)] and Vij is a CKM matrix element, without hadronic uncertainty if isospin is a perfect symmetry. Isospin, however, is broken not only by electroweak effects but also by the u and d quark mass difference. The latter drives π0η,η mixing and converts the isospin-perfect triangle relation between the Bππ amplitudes to a quadrilateral. The combined isospin-violating effects impact the extracted value of sin2α in a significant manner, particularly if the latter is small.