An EXAFS study of the structure of Fe3(CO)12 in solution
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1330-1333
- https://doi.org/10.1039/c39870001330
Abstract
Analysis of the Fe K-edge extended X-ray absorption fine structure (EXAFS) with multiple scattering calculations indicates that Fe3(CO)12 adopts primarily an all-terminal carbonyl co-ordination in light petroleum solution (mean Fe–Fe distance 2.65 Å), but that there is substantial population of bridging sites in a frozen CH2Cl2 solution (mean Fe–Fe distance 2.59 Å).Keywords
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