Transferability of Urey-Bradley Force Constants. VI. The Silyl Halides
- 1 February 1961
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 34 (2) , 574-577
- https://doi.org/10.1063/1.1700986
Abstract
Urey‐Bradley force constants have been fitted, by least squares, to the observed vibrational frequencies of SiH3F, SiH3Cl, SiH3Br, SiH3I and their fully deuterated analogs. The force constants have been correlated with other molecular parameters and, in the case of the nonbonded hydrogen‐halogen repulsions, have been discussed in terms of an inverse‐power potential function.Keywords
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