Double Carbonylation of Organohalogen Compounds Catalyzed by Polymer-Bound Palladium Complexes
- 1 March 1987
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 24 (3) , 289-300
- https://doi.org/10.1080/00222338708074446
Abstract
Palladium complex-catalyzed double carbonylation is a recently discovered reaction in organotransition metal chemistry. In this paper, some polymer-bound palladium complexes-polystyrylphosphine-palladium(0) complexes, poly-2-vinylpyridine-palladium(II) complexes, and poly-2-Af-vinylpyrrolidone-palladium(II) complexes have been prepared and characterized. The complexes were tested as catalysts in the double carbonylation reaction. Among these catalysts, polystyrylphos-phine-palladium(0) complexes showed good activity and selectivity, and can be easily recovered and reused. The influence of experimental parameters was investigated as well.Keywords
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