Structure, activity and selectivity relationships in propane ammoxidation to acrylonitrile on V–Sb oxides Part 3Modifications during the catalytic reaction and effect of feed composition

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Abstract
The change in surface reactivity up until steady-state behavior is reached in propane ammoxidation of a series of V–Sb-oxide catalysts with Sb:V ratios in the range 1–10 and prepared either by calcination or heat treatment in vacuum at 600°C is reported and analyzed in terms of the change in the structural feature

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