Hydrido Complexes of Iridium with a Tertiary Arsine
- 1 November 1968
- journal article
- research article
- Published by Wiley in Zeitschrift für anorganische und allgemeine Chemie
- Vol. 362 (5-6) , 318-322
- https://doi.org/10.1002/zaac.19683620512
Abstract
Two isomeric series (α and β) of hydrido complexes of iridium with methyldiphenyl arsine of the general formula IrHX2(Ph2AsMe)3 (X = Cl, Br or I) have been prepared and characterised. The α compounds are prepared by reacting the metal halide and the arsine in alcoholic medium with zinc and the corresponding halogen acid, while the β compounds are prepared by refluxing the metal halide and the arsine in alcoholic medium in presence of potassium hydroxide. The properties of these hydrido complexes are compared with the corresponding trihalogeno complexes of the general formula IrX3(Ph2AsMe)3. Hydrides of rhodium of the general formula RhHX2(Ph2AsMe)3, prepared earlier using hypophosphorous acid as reducing agent, can be made by other methods.Keywords
This publication has 5 references indexed in Scilit:
- The Formation of Hydridocobalamin and Its Stability in Aqueous SolutionsBiochemistry, 1963
- On the nature of LUNDEL and KNOWLES rhenide ionZeitschrift für anorganische und allgemeine Chemie, 1962
- Transition Metal-Hydrogen Compounds. I. Dipotassium Octahydridorhenate(VI)Journal of the American Chemical Society, 1961
- The chemistry of bivalent and trivalent iridium. Part III. Complexes of tertiary arsines with trivalent iridium halidesJournal and proceedings of the Royal Society of New South Wales, 1946
- A contribution to the chemistry of rheniumJournal of Research of the National Bureau of Standards, 1937