Inorganic compounds containing the trifluoroacetate group. Part VI. Reactions of molybdenum(II) trifluoroacetate with 2,2′-bipyridyl
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1041-1046
- https://doi.org/10.1039/dt9760001041
Abstract
The reaction between [Mo2(O2CCF3)4] and 2,2′-bipyridyl (1: 2) has been investigated in several solvents, and four different adducts, two 1:1 and two 1:2 compounds, have been isolated and characterised. The reaction between [Mo2(O2CCF3)4], 2,2′-bipyridyl, and [OEt3][BF4](1:2:2) has been shown to produce [Mo2(O2CCF3)2(bipy)2]-[BF4]2. Structures have been assigned to these compounds on the basis of spectroscopic data and the nature of the solution species, from which the various adducts originate, is discussed.Keywords
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