Oxidation of carbohydrates with chromium trioxide in acetic acid. II. Acetals. A new synthesis of ketoses
- 1 January 1971
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 24 (6) , 1219-1227
- https://doi.org/10.1071/ch9711219
Abstract
Oxidation of fully acylated methylene and benzylidene acetals of alditols with chromium trioxide in acetic acid yields fully acylated ketoses in their keto form. Derivatives of hex-3-uloses have been prepared by this method. Syntheses of 3,4-O-methylene-D-mannitol and 3,4-O-methylene-D-glucitol are described.Keywords
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