Thermodynamic studies of fluoroalcohols. Part 3.—The thermodynamics of transfer of five fluoroalcohols from the gas-phase to aqueous solution
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 69, 1577-1585
- https://doi.org/10.1039/f19736901577
Abstract
The free energies, enthalpies, entropies, and heat capacities of transfer of five fluoroalcohols from the gas-phase to aqueous solution at infinite dilution and at four temperatures have been determined. The results are primarily discussed in terms of the solute–solvent interactions between fluorinated alkyl-groups and water molecules in aqueous solution. Fluorocarbon groups promote in adjacent water molecules a structure which may possibly be ice-like in character.Keywords
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