THE THERMODYNAMICS OF LANTHANIDE COMPLEXING BY ACETYLACETONATE
- 1 February 1972
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 1 (3) , 179-182
- https://doi.org/10.1080/00958977208070760
Abstract
The thermodynamic parameters for the formation of the 1:1 complex between lanthanide ions and acetylacetonate in an aqueous medium of 0.10 M (NaClO4) are reported. These complexes are less stable than the analogous tropolonate complexes due to less exothermic enthalpies of chelation.Keywords
This publication has 11 references indexed in Scilit:
- Stability constants of manganese(II) and zinc(II) acetylacetonates in-propanol-water mixturesJournal of Chemical & Engineering Data, 1970
- The preparation, properties, and infra-red spectra (4000-170 cm−1) of dialkylamine complexes of cupric halidesJournal of Inorganic and Nuclear Chemistry, 1969
- The Coordination Chemistry of Yttrium and the Rare Earth Metal IonsChemical Reviews, 1965
- Complexes of the Lanthanide Elements with Kojate and Acetylacetonate IonsInorganic Chemistry, 1964
- Thermodynamic Properties of Rare Earth Complexes. III. Free Energy, Enthalpy, and Entropy Changes for the Formation of Rare Earth Acetate, Glycolate and Thioglycolate Complexes at 25 degrees C.Acta Chemica Scandinavica, 1964
- Thermodynamic Properties of Rare Earth Complexes. II. Free Energy, Enthalpy, and Entropy Changes for the Formation of Rare Earth Diglycolate and Dipicolinate Complexes at 25.00 degrees C.Acta Chemica Scandinavica, 1963
- Complexes of the lanthanide elements with α-hydroxy carboxylate ligandsJournal of Inorganic and Nuclear Chemistry, 1961
- Stability Relationships Among the Rare Earth AcetylacetonatesJournal of the American Chemical Society, 1960
- Studies on Coördination Compounds. XIV. The Determination of Enthalpy and Entropy Values for Several Bivalent Metal Ions and Cerium(III) with the Acetylacetonate IonThe Journal of Physical Chemistry, 1955
- Stability of Metal Chelates. IV. N,N'-Ethylenediaminediacetic Acid and N,N'-Ethylenediaminediacetic-N,N'-dipropionic AcidJournal of the American Chemical Society, 1952