Reaction of [Ir(cyclo-octa-1,5-diene){P(p-tolyl)3}2][nido-7,8-C2B9H12] with hydrogen; synthesis and X-ray structure of 3,9-[(H)2{P(p-tolyl)3}2Ir]-3,9-µ-(H)2-7,8-C2B9H10
- 1 January 1980
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 80-82
- https://doi.org/10.1039/c39800000080
Abstract
Treatment of the ion pair, [Ir(cod)(PR3)2][nido-7,8-C2B9H12](cod = cyclo-octa-1,5-diene; R = phenyl, p-tolyl) with hydrogen gave closo-3,3-(PR3)2-3-H-3,1,2-IrC2B9H11 and the novel nido-metallocarbaborane, 3,9-[cis-(H)2-trans-(PR3)2-Ir]-3,9-µ-(H)2-nido-7,8-C2B9H10.Keywords
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