Stereoconservative synthesis of Ipecac alkaloids from secologanin
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 367-369
- https://doi.org/10.1039/c39790000367
Abstract
Methyl 3,4-dihydrosecoxyloganin (2a), readily obtained from secologanin (1), has been converted with retention of chirality at C-2 and C-7 into a piperidone (5) which acts as a general synthetic precursor for Ipecac alkaloids exemplified by deoxytubulosine (8b), cephaeline (9b), and emetine (9c).This publication has 0 references indexed in Scilit: