Organic Syntheses by Means of Metal Complexes. ix. 1) Addition Reactions op Organic Polyhalides to Acrylic Monomers Catalyzed by Copper Complexes
- 3 January 1972
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 2 (1) , 51-53
- https://doi.org/10.1080/00397917208081641
Abstract
The addition reaction of organic polyhalides such as CCL4, trichloroacetate to acrylica monomers catalyzed by various catalysts proceeds in two ways. The first one is selective formation of 1:1 adduct and this reaction is catalyzed by copper or iron salts.2,3) when free radical generators such as benzoyl peroxide and metal carbonyls 4) are use as the catalyst, polymerization takes place. Termination step is predominant with the former catalysts and propagation step is predominant with the former catalysts and propagation step predominates over termination step with the latter catalysts.Keywords
This publication has 2 references indexed in Scilit:
- Copper Salts Induced Addition of Ethyl Trichloroacetate to OlefinsThe Journal of Organic Chemistry, 1964
- Some Novel Initiators of Vinyl PolymerizationJournal of Polymer Science Part C: Polymer Symposia, 1963