Preparation of ferrocenium phosphorus, arsenic, antimony, and bismuth halides. The structure of ferrocenium tetrachlorobismuthate
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 931-932
- https://doi.org/10.1039/c39760000931
Abstract
Eleven ferrocenium halogenopentelides (P, As, Sb, or Bi) have been prepared by the reaction of a group 5 element halide with ferrocene in an organic solvent; the structure of one of the products, [Fe(η5-C5H5)2][BiCl4], determined by X-ray crystallography, reveals an extended, one-dimensional anion of irregular, edgesharing BiCl6 3– octahedra.Keywords
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