Enantioselective Ion-Association Mode between the Tris(ethylenediamine)cobalt(III) Cation and the Bis(μ-(−)589-2,3-dimethyltartrato)diantimonate(III) Anion in Solution
- 1 June 1987
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 60 (6) , 2283-2285
- https://doi.org/10.1246/bcsj.60.2283
Abstract
By analyzing the intensity changes in the circular dichroism spectra, the association constants of the Λ-and Δ-[Co(en)3]3+ ions with the bis(μ-(−)589-2,3-dimethyltartrato)diantimonate(III) ion were determined to be 58.4±1.9 and 38.6±0.4 respectively in H2O (mol−1 dm3 at 25°C and μ=0.1 (NaClO4)). Based on these data together with the chromatographic data, the enantioselective association mode was discussed.This publication has 6 references indexed in Scilit:
- Mechanism of Chiral Recognition of Octahedral Metal Complexes Effected by Bis(μ-d-tartrato)-diantimonate(III) Anion in Solution. I. Association Models and Their Application to Some [Co(N)6]3+-Type ComplexesBulletin of the Chemical Society of Japan, 1986
- Mechanism of chromatographic separation of optically active metal complexesJournal of Chromatography A, 1984
- Chromatographic resolution of metal complexes on sephadex ion exchangersCoordination Chemistry Reviews, 1979
- Stereochemical Aspects of Optical Resolution of Octahedral Metal Chelates by Liquid ChromatographyJournal of Liquid Chromatography, 1979
- Chromatographic study of optical resolutionJournal of Chromatography A, 1978
- Studies of C-Substituted Tartaric Acid. I. The Preparation of Optically Active 2-Methyltartaric and 2, 3-Dimethyltartaric AcidBulletin of the Chemical Society of Japan, 1966