One- and Two-Dimensional Silver-Coordination Networks Containing π-Sandwiched Silver−Silver Interactions
- 28 March 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 41 (9) , 2543-2547
- https://doi.org/10.1021/ic010795q
Abstract
The self-assembly of coordination networks from reaction of 2,4,6-trimesityl-1,3,5-triazine and silver(I) trifluoroacetate is described. A one-dimensional linear polymer is formed from solutions deficient in silver while a two-dimensional, graphite-like sheet is formed from solutions containing 3 equiv of silver per triazine. The structurally similar networks both contain triazine rings separated by two trifluoroacetate-bridged silver atoms. The two silver atoms are effectively sandwiched between two mesityl rings with intermediate arene−silver interactions. The silver−silver bond lengths are 2.9731(4) and 2.9246(5) Å in the one-dimensional network and 2.8842(4) Å in the two-dimensional network.Keywords
This publication has 16 references indexed in Scilit:
- Design and Synthesis of a Sterically Hindered Pyridine and Its Encapsulation of Silver(I) CationInorganic Chemistry, 2001
- Calamitics, Cubics, and ColumnarsLiquid-Crystalline Complexes of Silver(I)Accounts of Chemical Research, 2000
- Dendrimer−Silver Complexes and Nanocomposites as Antimicrobial AgentsNano Letters, 2000
- Nanoporous Structures by DesignPublished by Wiley ,2000
- Molecular self-assemblies through coordinationPublished by Elsevier ,2000
- New Linear Coordination Polymers Based on Copper(I) and 4,7-Phenanthroline: Structure Dependence on Solvent and CounteranionInorganic Chemistry, 1999
- The Role of Bridging Ligands in Controlling Electronic and Magnetic Properties in Polynuclear ComplexesAccounts of Chemical Research, 1998
- Supramolecular ChemistryPublished by Wiley ,1995
- One-dimensional coordination polymers: Applications to material scienceCoordination Chemistry Reviews, 1993
- Notiz zur Darstellung von arylsubstituierten ImidazolenEuropean Journal of Inorganic Chemistry, 1973