Radical annulation: a method for preparation of carbocycles
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 980-982
- https://doi.org/10.1039/c39850000980
Abstract
β-Acetylenic radicals, e.g., (6b) and (12), generated in three steps from epoxides or in two steps from α-halogenoketones, respectively, react with electron-deficient olefins to produce five-membered carbocycles by a process of conjugate addition and 5-exo-digonal closure.Keywords
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