Octopus-porphyrins: their assembly and oxygen-binding in aqueous medium
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 728-730
- https://doi.org/10.1039/c39930000728
Abstract
Amphiphilic tetraphenylporphyrins having four alkyl phosphocholine groups on each side of the ring plane (octopus-porphyrins) form fibrous aggregates in dilute aqueous solution; the vesicles, constituted by iron(II) derivative–1-dodecyl-2-methylimidazole (DMIm), have the ability to bind dioxygen reversibly in aqueous medium.Keywords
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