Tris(trimethylsilyl)methantellurenylhalogenide (Me3Si)3CTeX (X = Cl, Br, I): Synthese stabiler Alkantellurenylhalogenide
- 1 July 1989
- journal article
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 122 (7) , 1255-1256
- https://doi.org/10.1002/cber.19891220707
Abstract
Tris (trimethylsilyl)methanetellurenyl Halides (Me3Si)3 CTex (X = Cl, Br, I): Synthesis of Stable Alkanetellurenyl HalidesThe first stable and isolable alkanetellurenyl halides, tris(trimethylsilyl)methanetellurenyl chloride, bromide, and iodide (1a–c) are obtained quantitatively by halogenolysis of bis[tris‐(trimethylsilyl)methyl] ditelluride with SO2Cl2, Br2, and I2, respectively. Their synthetic potential is examplified by transformation to methyl tris(trimethylsilyl)methyl telluride (2) and phenyl tris(trimethylsilyl)methyl telluride (3).Keywords
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