Umlagerungsreaktionen von lithiierten Silylhydroxylaminen mit Fluorsilanen / Rearrangement Reactions of Lithiated Silylhydroxylamines with Fluorosilanes
Open Access
- 1 November 1981
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 36 (11) , 1356-1360
- https://doi.org/10.1515/znb-1981-1102
Abstract
Halogenosilanes, with the exception of CH3SiF3 and SiF4, react with lithiated bis-(trimethylsilyl)hydroxylamine in ether to yield substituted hydroxylamines, and LiF. In the analogous reaction with trifluoromethylsilane and tetrafluorosilane the products undergo an intramolecular rearrangement to form silylaminosiloxanes.Keywords
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