One-electron oxidation of enol phosphates, enol phosphites and enol phosphinates. Evidence for an unprecedented P–O bond cleavage in phosphoenol radical cations in solution1
- 1 January 1996
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 2349-2350
- https://doi.org/10.1039/cc9960002349
Abstract
For the first time phosphoenol radical cations are generated in solution and monitored by cyclic voltammetry and EPR; the sterically congested radical cations undergo an unprecedented P–O bond cleavage, the kinetics of which are determined.Keywords
This publication has 24 references indexed in Scilit:
- α-Umpolung of Ketones and Aldehydes via the Corresponding Silyl Enol Ether Cation RadicalsChemistry Letters, 1994
- Umpolung of ketones via enol radical cationsPublished by Springer Nature ,1994
- Ketene-diene [4 + 2] cycloaddition products via cation radical initiated Diels-Alder reaction or vinylcyclobutanone rearrangementJournal of the American Chemical Society, 1993
- Electron transfer initiated Diels-Alder reaction with allenes as dienophilesTetrahedron Letters, 1993
- Oxidative cyclization of .delta.,.epsilon.- and .epsilon.,.zeta.-unsaturated enol silyl ethers and unsaturated siloxycyclopropanesThe Journal of Organic Chemistry, 1992
- Ammoniumyl Salt‐Induced Diels‐Alder Reaction of Ketenes—Control of [2 + 2] vs. [4 + 2] SelectivityAngewandte Chemie International Edition in English, 1991
- Photochemically induced radical-cation Diels-Alder reaction of indole and electron-rich dienesThe Journal of Organic Chemistry, 1991
- One electron more, One electron less. What does it change? Activations Induced by electron Transfer. The electron, an activating messenger.Tetrahedron, 1990
- Cation radical cycloadditions and related sigmatropic reactionsTetrahedron, 1989
- Electron Transfer Reactions in Organic ChemistryPublished by Springer Nature ,1987