Novel 1,4-Palladium Migration in Organopalladium Intermediates Derived from o-Iodobiaryls
- 9 November 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 124 (48) , 14326-14327
- https://doi.org/10.1021/ja027548l
Abstract
A novel 1,4-palladium migration in organopalladium intermediates derived from o-iodobiaryls has been observed under modified Heck reaction conditions. This migration process can be switched “on” or “off” by simply choosing the appropriate reaction conditions.Keywords
This publication has 11 references indexed in Scilit:
- Synthesis of 2H-1-Benzopyrans via Palladacycles with a Metal-Bonded Stereogenic CarbonOrganic Letters, 2002
- C−H Activation and Palladium Migration within Biaryls under Heck Reaction ConditionsOrganic Letters, 2002
- Synthesis of Polycyclic Aromatic Hydrocarbons by the Pd-Catalyzed Annulation of AlkynesThe Journal of Organic Chemistry, 1997
- The asymmetric Heck reactionTetrahedron, 1997
- Heck Reactions under Microwave Irradiation in Solvent-Free ConditionsSynlett, 1997
- The intramolecular Heck reactionContemporary Organic Synthesis, 1996
- Fine Feathers Make Fine Birds: The Heck Reaction in Modern GarbAngewandte Chemie International Edition in English, 1995
- Recent Developments and New Perspectives in the Heck ReactionAccounts of Chemical Research, 1995
- Application of intramolecular Heck reactions for forming congested quaternary carbon centers in complex molecule total synthesisPublished by Walter de Gruyter GmbH ,1994
- Palladium-catalysed vinylation of organic halides under solid–liquid phase transfer conditionsJournal of the Chemical Society, Chemical Communications, 1984