[H3N(CH2)7NH3]8(CH3NH3)2Sn(iv)Sn(ii)12I46? a mixed-valent hybrid compound with a uniquely templated defect-perovskite structure
- 19 November 2004
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 48-50
- https://doi.org/10.1039/b411322e
Abstract
The incorporation of H3N(CH2)7NH3 with CH3NH3SnI3 resulted in the formation of a mixed-valent and semiconducting (Eg = 0.84 eV) organic-based perovskite, [H3N(CH2)7NH3]8(CH3NH3)2Sn(IV)Sn(II)12I46, with a unique 3D defect-perovskite structure with ordered vacancies at the Sn and I sites.Keywords
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