Extraordinary acceleration of phosphodiester hydrolyses by thorium cations
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 17,p. 1639-1640
- https://doi.org/10.1039/a703568c
Abstract
Th IV cations in aqueous Brij micelles strongly promote the hydrolyses of several phosphodiester substrates; in the case of bis(p-nitrophenyl)phosphate 1, the observed rate constant (0.028 s - 1 ) represents an acceleration of ca 2.8 billion.Keywords
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