Cs3Fe5O(OH)(AsO4)5: a novel iron(III) arsenate containing four-, five- and six-coordinated iron atoms
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 9,p. 1061-1062
- https://doi.org/10.1039/cc9960001061
Abstract
A novel iron(III) arsenate is synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, which reveals a framework structure of vertex- and edge-sharing Fe–O polyhedra crosslinked by vertex-sharing AsO4 tetrahedral in a manner that generates tunnels and cavities occupied by Cs+ cations.Keywords
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